I'm sorry to hear you're having some issues with one of your PDFs. But we're happy to help! I will need a bit more information to assist you, though. If you could email us at social_support(at)constantcontact(dot)com with your username, the name of the PDF you are having trouble with, and a reference to this post and we can better assist you in resolving the issue.
When you say it will not download do you mean when clicking on a hyperlink in the email; it does not download to your computer? Or it won't display in your email?
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